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State Key Laboratory of Genetic Resources and Evolution, Key Laboratory of Healthy Aging Research of Yunnan Province, Kunming Key Laboratory of Healthy Aging Study, Kunming Institute of Zoology, Chinese Academy of Sciences, Kunming 650201, China 2

Specifically, constructing hierarchically porous architectures provides the structural foundation for balancing high ion accessibility with rapid transport kinetics, while the directional introduction of multiple heteroatoms enables the synergistic enhancement of electric double-layer storage, strong pseudocapacitance, and highly reversible chemisorption through electronic structure modulation and surface chemical modification, thus comprehensively improving the overall electrode performance