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This effect is primarily attributed to methylxanthines, such as theobromine, which induces LES relaxation through a mechanism similar to caffeine (Reference Fredholm190)

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Over time, this can wear down your intestinal barrier, creating tiny gaps in the gut wall a condition known as leaky gut. When the gut barrier is compromised, substances that should stay inside your digestive tract like bacterial toxins, undigested food particles, and inflammatory compoundscan leak into the bloodstream

When you take oral supplements, up to 80% of those active ingredients might be lost during digestion

Inhibitors of arachidonic acid metabolism: effects on rat striatal dopamine release and uptake